In a scattering problem, the main objective is solving the Schrödinger equation

$H\psi=(K+V)\psi=E\psi$

where H is the total Hamiltonian of the scattering system in the center of momentum, K is the kinetic energy and V is the potential energy. We seek for a solution $\psi$,

$\displaystyle \psi_{k}^{+}(r)=e^{i\vec{k}\cdot \vec{r}}+f(\theta)\frac{e^{ikr}}{kr}$

The solution can be decomposed

$\displaystyle \psi_{k}^{+}(r)=R_{l}(k,r)Y_{lm}(\theta,\phi)=\frac{u_{l}(k,r)}{kr}Y_{lm}(\theta,\phi)$

The solution of $u_{l}(k,r)$ can be solve by Runge-Kutta method on the pdf

$\displaystyle \left(\frac{d^2}{d\rho^2} + 1 - \frac{l(l+1)}{\rho^2} \right)u_{l}(k,\rho)=U(\rho)u_{l}(k,\rho)$

where $\rho=kr, k=\sqrt{2\mu E}/\hbar, \mu=(m_1+m_2)/(m_1 m_2)$ and $U=V/E$.

For $U = 0$, the solution of $u_l$ is

$\displaystyle u_{l}(k,r)=\hat{j}_l(\rho) \xrightarrow{r\rightarrow \infty} \sin(r') = \frac{e^{ir'}-e^{-ir'}}{2i}$

where $r' = kr-l\pi/2$ and $\hat{j}_l$ is the Riccati-Bessel function. The free wave function is

$\displaystyle \phi_k(r)=e^{i\vec{k}\cdot\vec{r}}=\sum\limits_{l=0} P_l(\cos(\theta)) \frac{2l+1}{2ikr}i^l (e^{ir'}-e^{-ir'})$

where $P_l(x)$ is the Legendre polynomial.

Note that, if we have Coulomb potential, we need to use the Coulomb wave instead of free wave, because the range of coulomb force is infinity.

For $U\neq 0$, the solution of $u_l(r can be found by Runge-Kutta method, where R is a sufficiency large that the potential $V$ is effectively equal to 0.  The solution of $u_l(r>R)$ is shifted

$\displaystyle u_{l}(k,r>R)=\hat{j}_l(\rho)+\beta_l \hat{n}_l(\rho) \xrightarrow{r\rightarrow \infty} \frac{1}{2i}(S_l e^{ir'}-e^{-ir'})$

where $S_l$ is the scattering matrix element, it is obtained by solving the boundary condition at $r = R$. The scattered wave function is

$\displaystyle \psi_k(r)=\sum\limits_{l=0} P_l(\cos(\theta)) (2l+1) i^l \frac{u_l(r)}{kr}$

put the scattered wave function and the free wave function back to the seeking solution, we have the $f(\theta)$

$\displaystyle f(\theta) = \sum\limits_{l=0} P_l(\cos(\theta)) \frac{2l+1}{2ik} (S_l - 1)$

and the differential cross section

$\displaystyle \frac{d\sigma}{d\Omega}=|f(\theta)|^2$.

In this very brief introduction, we can see

• How the scattering matrix $S_l$ is obtained
• How the scattering amplitude $f(\theta)$ relates to the scattering matrix

But what is scattering matrix? Although the page did not explained very well, especially how to use it.