For long time, i know the Hartree-Fock method is a way to find the mean-field, and the method is a mean-field theory. But how exactly the Hartree-Fock connects to the mean field, I have no idea. And occasionally, I mentioned the Hartree-Fock in its simplest form. Here, I will makes the connection crystal clear.

Hartree = self-consistence field

Fock = anti-symmetry wave function

Mean-field approximation, or in chemistry, self-consistence field approximation.

The full Hamiltonian is

Here, is one-body operator, and is two-body operator. I used Coulomb potential in the one-body operator, but it can be generalized as , and the mutual interaction can also be generalized as .

The idea of the mean-field approximation is that, what if, we can find a one-body potential , the mean-field, such that

Here, is the mean-field Hamiltonian, which represent most of the effective interaction to a particle, such that is the residual interaction, which is very small, and can be later treated as perturbation.

So, the problem is, how to find this mean field ?

Back to the form , we first construct a trial wave function,

Here, is the permutation operator, it can be 1-body exchange, 2-body exchange, and so on, but we will see that, only 1-body exchange (which is no change at all) and 2-body exchange are needed. is the Hartree wave function, it is a simple product of wave function of difference particles of difference states, or the diagonal product of the Slater determinant. In $\phi_\lambda(i) $, $\latex \lambda$ represents the state and is the “id” of the particle. Notice that

is the anti-symmetrization operator, it commute with Hamiltonian and a kind of projector operator,

Now, we evaluate the energy using this trial wave function.

Since the one-body operator only acts on the particle, any exchange will make the operator do nothing on the particle, then the orthogonality of the wave function makes the integration zero. Lets demonstrate on 2 particles case.

Notice that this is the one-body operator act on particle 1.

OK,

The is direct term, and the is the exchange term. This is a simplified notation, the first position is for the -th particle, and the second position is always for the -th particle.

Thus, the total energy is

We can factor out the ket in the above equation and get the Fock-operator, with a notation for the exchange term operator

Becareful on the ! I know the notation is messy, I know….

The Fock-operator is an effective one-body operator.

First, we put the trial basis wave function can get the Fock-matrix , then diagonalize it, get the new eigen-states. Use this set of new eigen-states to calculate agian and again until converged!

So, where is the mean-field? Lets expand the Fock-operator into the Hartree-Fock equation.

This is the mean-field!

Using the trial basis, we evaluate the Fock-matrix, that is equivalent to evaluate the mean-field.

In this post, the Hartree-fock for 2-body ground state is discussed. Unfortunately, that method is not the same in here. I would said, that method is only Hartree but not Fock. Since the method in that post can find a consistence field, but the ground state spatial is not anti-symmetric.

Since the spin-state is factored out, the spatial wave function of the case is identical. Thus, the exchange term is gone. The Slater determinant is

Here, are spin-state.

In general, the 2 particle system, the energy is

When , the direct term and exchange term cancelled. Thus, the “mean-field” is simply the Coulomb potential. Therefore, the method in that post is kind of getting around.

Some people may found that the Fock operator is

In this way, the direct term for will not be cancelled. In the case of 2 particle, the mean field is the Coulomb potential plus the average mutual interaction from the other particle.